Phosphorus trifluoride/PF3

Product Code GC-007
CAS Number 7783-55-3
Assay (purity) 99.8%
Purity Method by GC
Molecular Weight 87.969 g/mol
Form gas
Appearance colorless
Sensitivity moisture
Melting Point −151.5°C
Molecular Formula PF3
Linear Formula

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Safety Information

Signal Word Danger
Pictograms

Hazard Statements H302,H312,H314,H318,H330, H335
Precautionary Statements P260,P264,P270,P271,P280,P284,P301+P312,P301+P330+P331, P302+P352,P304+P340,P305+P351+P338,P310,P330,P363,P403+P233,P405,P501
UN 1955
Transport Description Compressed gas, toxic, n.o.s. (Phosphorus trifluoride)
Hazardous Class 2.3
Packing Group N/A
In TSCA Registry Yes

Certificates of Analysis (CoA)

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External Identifiers

Pubchem CID
SMILES FP(F)F
IUPAC Name trifluorophosphane
InchI Identifier InChI=1S/F3P/c1-4(2)3
InchI Key WKFBZNUBXWCCHG-UHFFFAOYSA-N

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Application of Trifluoride

Phosphorus trifluoride (PF3) is used in semiconductor manufacturing primarily as an etching and cleaning agent. PF3 is applied in plasma etching processes, where it can be used to selectively remove materials from semiconductor wafers. The advantage of PF3 over some other fluorinated gases is its lower global warming potential (GWP), making it a potentially more environmentally friendly option for certain etching applications.

PF3 can also be used in chamber cleaning processes for chemical vapor deposition (CVD) tools.

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